Integrated groundwater resource management in Indus Basin using satellite gravimetry and physical modeling tools

Reliable and frequent information on groundwater behavior and dynamics is very important for effective groundwater resource management at appropriate spatial scales. This information is rarely available in developing countries and thus poses a challenge for groundwater managers. The in situ data and groundwater modeling tools are limited in their ability to cover large domains. Remote sensing technology can now be used to continuously collect information on hydrological cycle in a cost-effective way. This study evaluates the effectiveness of a remote sensing integrated physical modeling approach for groundwater management in Indus Basin. The Gravity Recovery and Climate Experiment Satellite (GRACE)-based gravity anomalies from 2003 to 2010 were processed to generate monthly groundwater storage changes using the Variable Infiltration Capacity (VIC) hydrologic model. The groundwater storage is the key parameter of interest for groundwater resource management. The spatial and temporal patterns in groundwater storage (GWS) are useful for devising the appropriate groundwater management strategies. GRACE-estimated GWS information with large-scale coverage is valuable for basin-scale monitoring and decision making. This frequently available information is found useful for the identification of groundwater recharge areas, groundwater storage depletion, and pinpointing of the areas where groundwater sustainability is at risk. The GWS anomalies were found to favorably agree with groundwater model simulations from Visual MODFLOW and in situ data. Mostly, a moderate to severe GWS depletion is observed causing a vulnerable situation to the sustainability of this groundwater resource. For the sustainable groundwater management, the region needs to implement groundwater policies and adopt water conservation techniques.     

Chapter one: exposure measurements

Determining human exposure to suspended particulate concentrations requires measurements that quantify different particle properties in microenvironments where people live, work, and play. Particle mass, size, and chemical composition are important exposure variables, and these are typically measured with time-integrated samples on filters that are later submitted to laboratory analyses. This requires substantial sample handling, quality assurance, and data reduction. Newer technologies are being developed that allow in-situ, time-resolved measurements for mass, carbon, sulfate, nitrate, particle size, and other variables. These are large measurement systems that are more suitable for fixed monitoring sites than for personal applications. Human exposure studies need to be designed to accomplish specific objectives rather than to serve too many purposes. Resources need to be divided among study design, field sampling, laboratory analysis, quality assurance, data management, and data analysis phases. Many exposure projects allocated too little to the non-measurement activities.     

Routinization of job context and job content as related to employees' quality of working life: A study of Canadian nurses

The literature on routinization of work is both ambiguous and equivocal when its impact on quality of working life is considered. The classical management literature suggests that routinization of work has a positive influence on individual performance and by implication on the quality of working life resulting from the overall prosperity generated. However, more recent literature on job characteristics and job design argues that routinization of work has a negative impact on individual performance as it suppresses creative expression on the job. This paper suggests that these mixed findings are due to an inadequate theoretical grasp of the concept of routinization and presents empirical evidence which attempts to clarify the ambiguity. Data were collected from 1148 nurses working in anglophone hospitals in the greater Montreal area in the form of a field survey questionnaire. The results indicated that nurses who worked routine shifts perceived higher levels of quality of working life compared to those on non-routine shifts. The results also indicated that nurses who experienced high routinization in job content perceived lower levels of quality of working life compared to those nurses who experienced low routinization in job content. Implications of these findings for future research are discussed.     

Shiftwork and department-type related to job stress,work attitudes and behavioral intentions: A study of nurses

The present study examined the relationship of shiftwork and department-type with employees' job stress, stressors, work attitudes and behavioral intention. Data were collected by means of a structured questionnaire from nurses (N = 1148) working in eight hospitals in a large, metropolitan city in eastern Canada. One-way ANOVA, MANOVA and two-way ANOVA were used to analyze data. Results generally support the prediction that nurses working on fixed shifts were better off than nurses working on rotating shifts in terms of the dependent variables of the present study. The prediction that nurses working in non-intensive care departments were better off than nurses working in intensive care departments received mixed support at best. A few interaction effects of shiftwork × department-type on dependent variables were also noted. The impact of socio-demographic variables — age, marital status, cultural background (English- versus French-speaking) — on the above relationships were also analyzed. Results are discussed in light of the previous empirical evidence on shiftwork and department-type.     

Study on assessment of slope stability and mixed disposal of overburden in voids of Singrauli Coalfield

The mining industry can be considered the backbone of the Indian economy as well as facilitating the power that drives most of the other industries in the company. The overburden and waste rocks produced during coal mining are major concerns in regard to the amount of land that is required for their disposal, as well as the stability of dumps for these materials, which are of increasing height. Land reclamation issues are also a concern. In this work the adverse impacts caused by the dumping of overburden on land and acidic mine water on water bodies is discussed. Remote sensing tools were used along with the laboratory experimentation to assess the various impacts. This study also shows that silt released from waste dumps, can affected the angle of repose of the overburden dump slope. The angle of repose of the overburden materials varies with particle size composition. Thus, use of in‐pit crushers in large opencast mining operations can effectively reduce the area locked under the waste dumps. The acid neutralization potential of fly ash and overburden for the treatment of acid water was tested in the laboratory by using fly ash and waste rock materials on acidic coalfield water. The results are encouraging, and fly ash may prove to be a good acid neutralizer when used in conjunction of coal overburden material.     

A Hydraulic MultiModel Ensemble Framework for Visualizing Flood Inundation Uncertainty

While deterministic forecasts provide a single realization of potential inundation, the inherent uncertainty associated with forecasts also needs to be conveyed for improved decision support. The objective of this study was to develop an ensemble framework for the quantification and visualization of uncertainty associated with flood inundation forecast maps. An 11‐member ensemble streamflow forecast at lead times from 0 to 48 hr was used to force two hydraulic models to produce a multimodel ensemble. The hydraulic models used are (1) the International River Interface Cooperative along with Flow and Sediment Transport with Morphological Evolution of Channels solver and (2) the two‐dimensional Hydrologic Engineering Center‐River Analysis System. Uncertainty was quantified and augmented onto flood inundation maps by calculating statistical spread among the ensemble members. For visualization, a series of probability flood maps conveying the uncertainty in forecasted water extent, water depth, and flow velocity was disseminated through a web‐based decision support tool. The results from this study offer a framework for quantifying and visualizing model uncertainty in forecasted flood inundation maps.     

A first approximation kinetic model to predict methane generation from an oil sands tailings settling basin

A small fraction of the naphtha diluent used for oil sands processing escapes with tailings and supports methane (CH(4)) biogenesis in large anaerobic settling basins such as Mildred Lake Settling Basin (MLSB) in northern Alberta, Canada. Based on the rate of naphtha metabolism in tailings incubated in laboratory microcosms, a kinetic model comprising lag phase, rate of hydrocarbon metabolism and conversion to CH(4) was developed to predict CH(4) biogenesis and flux from MLSB. Zero- and first-order kinetic models, respectively predicted generation of 5.4 and 5.1 mmol CH(4) in naphtha-amended microcosms compared to 5.3 (+/-0.2) mmol CH(4) measured in microcosms during 46 weeks of incubation. These kinetic models also predicted well the CH(4) produced by tailings amended with either naphtha-range n-alkanes or BTEX compounds at concentrations similar to those expected in MLSB. Considering 25% of MLSB's 200 million m(3) tailings volume to be methanogenic, the zero- and first-order kinetic models applied over a wide range of naphtha concentrations (0.01-1.0 wt%) predicted production of 8.9-400 million l CH(4) day(-1) from MLSB, which exceeds the estimated production of 3-43 million l CH(4) day(-1). This discrepancy may result from heterogeneity and density of the tailings, presence of nutrients in the microcosms, and/or overestimation of the readily biodegradable fraction of the naphtha in MLSB tailings.     

Sources and environmental behavior of dechlorane plus--a review

Intensive research has been carried out in the past few years on the occurrence and behavior of dechlorane plus (DP) in the environment, biota and humans. This review summarizes the information and research results generated since DP was first identified in the environment in 2006. We describe the reported measurement methods for DP and provide an integrated picture of its occurrence and behavior as an environmental contaminant. DP in ambient air and sediments is characterized by strong source related concentration elevations and temporal trends reflecting commercial use. Long-range atmospheric transportation of DP has been observed in remote regions, indicating a global presence of DP. Levels of DP in biota and in humans further reinforce its source related distribution. The change in DP isomer ratio in various environmental matrices from commercial products indicates that the behavior of the two isomers is not the same in the environment or in biota. With only limited data available so far, the biomagnification of DP in aquatic biota has not been conclusively demonstrated. This review also looks at reported dechlorination products of DP that might be of interest in future research.     

Pb in medicinal plants from Jordan

This is the first report on Pb in medicinal herbs from Jordan. Medicinal herbs may present a health risk due to the presence of toxic metals. Seventy-nine dry medicinal plant samples were collected from herbalist shops in Jordan. The plants were digested with acids and analyzed for total Pb concentration using atomic absorption spectrometry. Mean Pb concentration was 15.9 μg/g on a dry weight basis. Our results show that Pb concentrations in Jordan medicinal plants are higher than published data in other countries. The highest level of 33.4 μg Pb/g was determined in Inula viscosa, and the lowest level of 3.0 μg Pb/g was found in Nigella sativa. Calculated daily intakes of Pb of most analyzed herbs were high; most of them are higher than recommended values by the world health organization (WHO). Fortunately, the herbs that contain the highest Pb levels are the less commonly used medicinal herbs in Jordan. The mean Pb levels in the most commonly, commonly and less commonly used herbs in Jordan are 13.9, 13.1 and 16.9 μg Pb/g, respectively. The average dietary intake of Pb through a mixture of these medicinal herbs consumption, assuming 5.0 g herbs is consumed daily, is 79.5 μg Pb/day, which is higher than the maximum daily limit allowed by WHO. We conclude that most of the medicinal plants consumed in Jordan contain significant amount of Pb, and therefore, people of Jordan should not consume large amounts of these herbs.     

The effect of air mass origin on the ambient concentrations of Be and Pb in Islamabad, Pakistan

Concentration of radionuclides ²¹⁰Pb and ⁷Be, having half lives of 22.3 years and 53.29 days, respectively, in the surface air samples of Islamabad (33.38° N, 73.10° E and Altitude ∼536 m asl.) are measured. The non-destructive technique of gamma-spectrometry, with a high purity germanium HPGe detector, was employed for the analysis of all samples. The annual average concentrations of ²¹⁰Pb and ⁷Be in the surface air samples were determined as 0.284 ± 0.15 and 3.171 ± 1.14 mBq m⁻³, respectively. Our results have shown a seasonal variation of the concentration of ⁷Be in air samples with high values for the spring season. High concentrations for ²¹⁰Pb are obtained when air masses originate from plain areas of Pothohar region, located in the South-West, West and North West of Islamabad. Our values of concentrations show a nice agreement with the relevant reported results.